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Instructor Videos
VIDEOS | RESOURCES |
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Introduction to Solid State Chemistry (00:08:14) Course Introduction > Download from iTunes U (MP4 - 18MB) > Download from Internet Archive (MP4 - 18MB) Donald Sadoway: The Missing Link to Renewable Energy |
Transcript (PDF) |
Structure of the Atom
TITLES | READINGS | LECTURE VIDEOS | LECTURE RESOURCES | HOMEWORK | FOR FURTHER STUDY |
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Introduction to Solid State Chemistry | [Saylor] 1, "Introduction to Chemistry." |
Lecture 1: Introduction to Solid State Chemistry (00:48:15) Lecture 1: Introduction to Solid State Chemistry > Download from iTunes U (MP4 - 205MB) > Download from Internet Archive (MP4 - 205MB) |
Lecture Slides (PDF - 3.2MB) |
› Textbook Problems |
› Supplemental Readings Davies, D. A. Waves, Atoms and Solids. Harlow Essex, UK: Longman Group United Kingdom, 1978. ISBN: 9780582441743. Brown, T. L., H. E. Lemay, and B. E. Bursten. Chemistry: The Central Science. Upper Saddle River, NJ: Prentice Hall, 1999. ISBN: 9780130103109. › People Democritus; Aristotle; John Dalton; Dmitri Mendeleev; Johann Dobereiner; John Newlands; Julius Meyer › Other OCW and OER Content |
The Periodic Table |
› Readings [Saylor] 1.6, "Isotopes and Atomic Masses." [Saylor] 1.7, "Introduction to the Periodic Table." [Saylor] 3.1, "The Mole and Molar Masses." [Saylor] 3.2, "Determining Empirical and Molecular Formulas." [Saylor] 3.3, "Chemical Equations." [Saylor] 3.4, "Mass Relationships in Chemical Equations." [Saylor] 7.1, "The History of the Periodic Table." (only read until "Mendeleev's Periodic Table") |
Lecture 2: The Periodic Table (00:48:57) |
› Textbook Problems |
› Supplemental Readings Emsley, J. The Elements. New York, NY: Oxford University Press, 1998. ISBN: 9780198558187. Weeks, M. E. Discovery of the Elements. Madison, WI: Journal of Chemical Education, 1968. Seaborg, Glenn T., and E.G. Valens. Elements of the Universe. New York, NY: E.P. Dutton & Co., 1958. ISBN: 9789999238939. Strathern, P. Mendeleyev's Dream: The Quest for the Elements. New York, NY: St. Martin's Press, 2001. ISBN: 9780140284140. Gordin, M. A Well-Ordered Thing: Dmitrii Mendeleev and the Shadow of the Periodic Table. New York, NY: 2004. ISBN: 9780465027750. Mendeleyev, Dmitri. The Principles of Chemistry. New York, NY: Longmans Green and Co., 1897. Dalton, John. A New System of Chemical Philosophy. New York, NY: Philosophical Library, 1964. Cardwell, D. John Dalton and the Progress of Science. New York, NY: Barnes and Noble, 1968. Kargon, Robert H. The Rise of Robert Millikan: Portrait of a Life in American Science. New York, NY: Cornell University Press, 1982. ISBN: 9780801414596. Millikan, Robert A. Electrons, Protons, Photons, Neutrons, Mesotrons, and Cosmic Rays. Chicago, IL: University of Chicago Press, 1947. › People John Dalton; Jöns Berzelius; Amedeo Avogadro; Michael Faraday; Robert Millikan - 1923 Nobel Prize in Physics; Democritus; Aristotle; Dmitri Mendeleev; Alexander Borodin; Charles-Augustin de Coulomb; William Thomson, Lord Kelvin › Culture Borodin, Alexander P. "Polovtsian Dances." Prince Igor. Available as Ballet Music from Operas. Performed by New York Philharmonic, conducted by Leonard Bernstein. New York, NY: Sony, 1993. Lehrer, T. The Remains of Tom Lehrer. Los Angeles, CA: Warner Archives/Rhino, 2000. › Other OCW and OER Content |
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Atomic Models: Rutherford & Bohr |
› Readings Archived Lecture Notes #1 (PDF), Sections 1-3 [Saylor] 1.5, "The Atom." [Saylor] 6.2, "The Quantization of Energy." [Saylor] 6.3, "Atomic Spectra and Models of the Atom." |
Lecture 3: Atomic Models: Rutherford & Bohr (00:50:26) Lecture 3: Atomic Models: Rutherford & Bohr > Download from iTunes U (MP4 - 214MB) > Download from Internet Archive (MP4 - 214MB) |
› Textbook Problems |
› Supplemental Readings Ottaviani, J. Suspended in Language: Niels Bohr's Life, Discoveries, and the Century He Shaped. GT Labs: Ann Arbor, MI, 2004. ISBN: 9780978803728. Rozental, S. Niels Bohr: His Life and Work as Seen by His Friends and Colleagues. New York, NY: Wiley, 1967. Bohr, Niels H. D. On the Constitution of Atoms and Molecules. New York, NY: W.A. Benjamin, 1963. Bohr, Niels H. D. Atomic Physics and Human Knowledge. New York, NY: Wiley, 1958. Bohr, Niels. "On the Constitution of Atoms and Molecules." Philosophical Magazine Series 6 26 (July 1913): 1-15. Cathcart, B. The Fly in the Cathedral: How a Small Group of Cambridge Scientists Won the Race to Split the Atom. New York, NY: Penguin, 2005. ISBN: 9780670883219. Andrade, E. N. R utherford and the Nature of the Atom. Garden City, NY: Doubleday, 1964. Frayn, M. Copenhagen: A Play in Two Acts. New York, NY: S. French, 2000. Miller, D. P. Discovering Water: James Watt, Henry Cavendish and the Nineteenth Century Water Controversy. Burlington, VT: Ashgate, 2004. ISBN: 9780754631774. › People Joseph Thompson - 1906 Nobel Prize in Physics; Ernest Rutherford - 1908 Nobel Prize in Chemistry; Johannes Geiger; Ernest Marsden; Max Planck - 1918 Nobel Prize in Physics; Albert Einstein - 1921 Nobel Prize in Physics; Niels Bohr - 1922 Nobel Prize in Physics; Robert Millikan - 1923 Nobel Prize in Physics; Henry Cavendish; Werner Heisenberg - 1932 Nobel Prize in Physics; Harold Urey - 1934 Nobel Prize in Chemistry; Charles-Augustin de Coulomb; James Prescott Joule › Other OCW and OER Content |
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Matter/Energy Interactions: Atomic Spectra |
› Readings Archived Lecture Notes #1 (PDF), Sections 3, 5 [Saylor] 6.3, "Atomic Spectra and Models of the Atom." |
Lecture 4: Matter/Energy Interactions: Atomic Spectra (00:51:43) Lecture 4: Matter/Energy Interactions: Atomic Spectra > Download from iTunes U (MP4 - 220MB) > Download from Internet Archive (MP4 - 220MB) |
› Textbook Problems [Saylor] 6.3, "Atomic Spectra and Models of the Atom." |
› Supplemental Readings Payne-Gaposchkin, Cecilia H. Cecilia Payne-Gaposchkin: An Autobiography and Other Recollections. New York, NY: Cambridge University Press, 1996. ISBN: 9780521482516. Baade, W., and Cecilia Payne. Evolution of Stars and Galaxies. Cambridge, MA: Harvard University Press, 1963. Payne-Gaposchkin, Cecilia H. Stars and Clusters. Cambridge, MA: Harvard University Press, 1979. ISBN: 9780674834408. › People Niels Bohr - 1922 Nobel Prize in Physics; Max Planck - 1918 Nobel Prize in Physics; Johann Balmer; Amedeo Avogadro; Michael Faraday; Cecilia Payne; Ernest Rutherford - 1908 Nobel Prize in Chemistry; Anders Jonas Ångström; James Prescott Joule; Charles-Augustin de Coulomb; Alessandro Volta › Other OCW and OER Content |
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Electron Shell Model & Quantum Numbers |
› Readings Archived Lecture Notes #1 (PDF), Section 3 [Saylor] 6.5, "Atomic Orbitals and Their Energies." [Saylor] 6.6, "Building Up the Periodic Table." |
Lecture 5: Electron Shell Model & Quantum Numbers (00:52:08) Lecture 5: Electron Shell Model & Quantum Numbers > Download from iTunes U (MP4 - 221MB) > Download from Internet Archive (MP4 - 221MB) |
› Textbook Problems [Saylor] 6.5, "Atomic Orbitals and Their Energies." |
› Supplemental Readings Michelson, Albert A. Studies in Optics. Chicago, IL: University of Chicago Press, 1927. Sommerfeld, Arnold. Atomic Structure and Spectral Lines. New York, NY: E.P. Dutton, 1931. Sommerfeld, Arnold. Optics. New York, NY: Academic Press, 1964. Dick, Harold G. The Golden Age of the Great Passenger Airships, Graf Zeppelin and Hindenburg. Washington, DC: Smithsonian Institution Press, 1985. ISBN: 9781560982197. › People Niels Bohr - 1922 Nobel Prize in Physics; Max Planck - 1918 Nobel Prize in Physics; Johann Balmer; Johannes Rydberg; Otto Stern - 1943 Nobel Prize in Physics; Walter Gerlach; James Franck, Gustav Hertz - 1925 Nobel Prize in Physics; Albert Michelson - 1907 Nobel Prize in Physics; Edward Morley; Pieter Zeeman, Hendrik Lorentz - 1902 Nobel Prize in Physics; Johannes Kepler; Arnold Sommerfeld; Anders Jonas Ångström; Alessandro Volta › Other OCW and OER Content |
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Particle-Wave Duality |
› Readings Archived Lecture Notes #1 (PDF), Section 3 Archived Lecture Notes #2 (PDF), Section 3 [Saylor] 6.4, "The Relationship between Energy and Mass." [Saylor] 6.6, "Building Up the Periodic Table." |
Lecture 6: Particle-Wave Duality (00:50:58) | Lecture Slides (PDF - 1.7MB) |
› Textbook Problems [Saylor] 6.4, "The Relationship between Energy and Mass." |
› Supplemental Readings Schrödinger, Erwin. My View of the World. Cambridge, MA: University Press, 1964. Schrödinger, Erwin. Collected Papers on Wave Mechanics: Together With His Four Lectures on Wave Mechanics. New York, NY: Chelsea Publications, 1982. ISBN: 9780821829769. Peat, F. David. From Certainty to Uncertainty: The Story of Science and Ideas in the Twentieth Century. Washington, DC: Joseph Henry Press, 2002. ISBN: 9780309076418. Rigden, John S. Hydrogen: The Essential Element. Cambridge, MA: Harvard University Press, 2002. ISBN: 9780674012523. Frayn, M. Copenhagen: A Play in Two Acts. New York, NY: S. French, 2000. Powers, Thomas. Heisenberg's War: The Secret History of the German Bomb. New York, NY: Knopf, 1993. ISBN: 9780306810114. › People Louis de Broglie - 1929 Nobel Prize in Physics; Werner Heisenberg - 1932 Nobel Prize in Physics; Erwin Schrödinger - 1933 Nobel Prize in Physics; Wolfgang Pauli - 1945 Nobel Prize in Physics; Friedrich Hund; Clinton Davisson - 1937 Nobel Prize in Physics; Lester Germer › Other OCW and OER Content |
The Aufbau Principle; Photoelectron Spectroscopy |
› Readings Archived Lecture Notes #1 (PDF), Section 4 [Saylor] 6.6, "Building Up the Periodic Table." [Saylor] 7.3, "Energetics of Ion Formation." |
Lecture 7: The Aufbau Principle; Photoelectron Spectroscopy (00:47:59) Lecture 7: The Aufbau Principle; Photoelectron Spectroscopy > Download from iTunes U (MP4 - 201MB) > Download from Internet Archive (MP4 - 201MB) |
› Textbook Problems |
People |
Self-Assessment: Structure of the Atom
SCOPE | WEEKLY QUIZ | EXAM PROBLEMS | EXAM HELP SESSION VIDEOS | SUPPLEMENTAL PROBLEMS |
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Structure of the Atom | Exam Solutions Key (PDF) |
› Video Clips
Clip 1: Exam 1, Problem 1 (00:10:00)
Clip 1: Exam 1, Problem 1 > Download from iTunes U (MP4 - 23MB) > Download from Internet Archive (MP4 - 23MB) Clip 2: Exam 1, Problem 2 > Download from iTunes U (MP4 - 45MB) > Download from Internet Archive (MP4 - 45MB) Clip 3: Exam 1, Problem 4 > Download from iTunes U (MP4 - 32MB) > Download from Internet Archive (MP4 - 32MB) Clip 4: Exam 1, Problem 6 > Download from iTunes U (MP4 - 36MB) > Download from Internet Archive (MP4 - 36MB) |
Bonding and Molecules
TITLES | READINGS | LECTURE VIDEOS | LECTURE RESOURCES | HOMEWORK | FOR FURTHER STUDY |
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Ionic Crystals; Born-Haber Cycle |
› Readings Archived Lecture Notes #1 (PDF), Sections 6, 7 Archived Lecture Notes #2 (PDF), Sections 1, 2 [Saylor] 7.3, "Energetics of Ion Formation." [Saylor] 8.1, "An Overview of Chemical Bonding." [Saylor] 8.2, "Ionic Bonding." [Saylor] 8.3, "Lattice Energies in Ionic Solids." [Saylor] 12.5, "Correlation between Bonding and the Properties of Solids." |
Lecture 8: Ionic Crystals; Born-Haber Cycle (00:50:30) Lecture 8: Ionic Crystals; Born-Haber Cycle > Download from iTunes U (MP4 - 214MB) > Download from Internet Archive (MP4 - 214MB) |
Lecture Slides (PDF - 1.2MB) |
› Textbook Problems |
› Supplemental Readings Born, Max. My Life: Recollections of a Nobel Laureate. New York, NY: Scribner, 1978. ISBN: 9780684156620. Born, Max. Physics in My Generation. New York, NY: Springer-Verlag, 1969. Born, Max. Atomic Physics. New York, NY: Hafner Publications, 1970. ISBN: 9780486659848. Stoltzenberg, Dietrich. Fritz Haber: Chemist, Nobel Laureate, German, Jew. Philadelphia, PA: Chemical Heritage Press, 2004. ISBN: 9780941901246. Charles, Daniel. Master Mind: The Rise and Fall of Fritz Haber, the Nobel Laureate who Launched the Age of Chemical Warfare. New York, NY: Ecco, 2005. ISBN: 9780060562724. › People Fritz Haber - 1918 Nobel Prize in Chemistry; Charles Hall; Paul Heroult; Germain Hess; Erwin Madelung; Max Born - 1954 Nobel Prize in Physics › Other OCW and OER Content |
Drawing Lewis Structures |
› Readings Archived Lecture Notes #2 (PDF), Section 3 [Saylor] 7.3, "Energetics of Ion Formation." [Saylor] 8.4, "Introduction to Lewis Dot Structures." [Saylor] 8.5, "Lewis Structures and Covalent Bonding." [Saylor] 8.6, "Exceptions to the Octet Rule." [Saylor] 8.8, "Properties of Covalent Bonds." [Saylor] 8.9, "Polar Covalent Bonds." |
Lecture 9: Drawing Lewis Structures (00:52:01) |
› Textbook Problems |
› Supplemental Readings Molina, Mario J. and Rowland, F. S. "Stratospheric sink for chlorofluoromethanes: chlorine atomc-atalysed destruction of ozone." Nature 249 (June 28, 1974): 810-812. › People › Other OCW and OER Content |
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Hybridized & Molecular Orbitals; Paramagnetism |
› Readings Archived Lecture Notes #2 (PDF), Section 3 [Saylor] 9.2, "Localized Bonding and Hybrid Atomic Orbitals." [Saylor] 9.3, "Delocalized Bonding and Molecular Orbitals." [Saylor] 9.4, "Combining the Valence Bond and Molecular Orbital Approaches." |
Lecture 10: Hybridized & Molecular Orbitals, Paramagnetism (00:50:50) Lecture 10: Hybridized & Molecular Orbitals, Paramagnetism > Download from iTunes U (MP4 - 216MB) > Download from Internet Archive (MP4 - 216MB) |
Lecture Slides (PDF - 2.1MB) |
› Textbook Problems |
PeopleWolfgang Pauli - 1945 Nobel Prize in Physics › Other OCW and OER Content 5.111 Principles of Chemical Science: Lecture 14: Molecular Orbital Theory and Lecture 15: Valence Bond Theory and Hybridization |
The Shapes of Molecules |
› Readings [Saylor] 9.1, "Predicting the Geometry of Molecules and Polyatomic Ions." |
Lecture 11: The Shapes of Molecules (00:47:03) | Lecture Slides (PDF - 1.2MB) |
› Textbook Problems |
› Other OCW and OER Content |
Intermolecular Forces |
› Readings Archived Lecture Notes #2 (PDF), Section 4 [Saylor] 11.2, "Intermolecular Forces." [JS] 2.5, "The Secondary, or van der Waals, Bond." |
Lecture 12: Intermolecular Forces (00:34:47) | Lecture Slides (PDF) |
› Textbook Problems [Saylor] 11.2, "Intermolecular Forces." |
› Supplemental Readings Gavroglu, Kostas. Fritz London: A Scientific Biography. New York, NY: Cambridge University Press, 1995. ISBN: 9780521023191. Israelachvili, Jacob. Intermolecular and Surface Forces. New York, NY: Academic Press, 1992. ISBN: 9780123751812. › People › Other OCW and OER Content |
Self-Assessment: Bonding and Molecules
Electronic Materials
TITLES | READINGS | LECTURE VIDEOS | LECTURE RESOURCES | HOMEWORK | FOR FURTHER STUDY |
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Band Theory of Solids |
› Readings |
Lecture 13: Band Theory of Solids (00:49:57) | Lecture Slides (PDF) |
› Supplemental Readings Bloch, Felix. "Über die Quantenmechanik der Elektronen in Kristallgittern." Zeitschrift für Physik A: Hadrons and Nuclei 52 (1928): 555-600. (Note: this article is in German.) Heitler, Walter, and Fritz London. "Wechselwirkung neutraler Atome und homöopolare Bindung nach der Quantenmechanik." Zeitschrift für Physik A: Hadrons and Nuclei 44 (1927): 455-472. (Note: this article is in German.) › People › Other OCW and OER Content |
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Semiconductors |
› Readings Archived Lecture Notes #3 (PDF) [Saylor] 12.6, "Bonding in Metals and Semiconductors." |
Lecture 14: Semiconductors (00:47:16) | Lecture Slides (PDF - 2.5MB) |
› Supplemental Readings Heitler, Walter, and Fritz London. "Wechselwirkung neutraler Atome und homöopolare Bindung nach der Quantenmechanik." Zeitschrift für Physik A: Hadrons and Nuclei 44 (1927): 455-472. (Note: this article is in German.) › People James Clerk Maxwell; Ludwig Boltzmann; William Shockley, John Bardeen, Walter Brattain – 1956 Nobel Prize in Physics › Other OCW and OER Content The resources listed below are selected from a wide variety of sites covering semiconductors and their applications. Motivated users are encouraged to search MIT OpenCourseWare and other sites for more advanced material based on their specific interests. Introduction to Semiconductors PV CDROM: Module 3: PN Junction Introduction to Semiconductors, Doped Semiconductors 5.112 Principles of Chemical Science: Lecture 14: Distribution of Molecular Energies and Starts 8:15 in Lecture 34: Bonding in Metals and Semiconductors 6.012 Microelectronic Devices and Circuits: Spring 2009, Fall 2009 |
Self-Assessment: Electronic Materials
SCOPE | WEEKLY QUIZ | EXAM PROBLEMS | EXAM HELP SESSION VIDEOS | SUPPLEMENTAL PROBLEMS |
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Electronic Materials | Quiz Solutions Key (PDF) | Exam Solutions Key (PDF) | Clip 1: Exam 2, Problem 3 (00:20:00) |
Supplemental Exam Problems (PDF) Supplemental Exam Solutions Key (PDF) |
Crystalline Materials
TITLES | READINGS | LECTURE VIDEOS | LECTURE RESOURCES | HOMEWORK | FOR FURTHER STUDY |
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Introduction to Crystallography |
› Readings Archived Lecture Notes #4 (PDF), Sections 1-3 [Saylor] 12.1, "Crystalline and Amorphous Solids." [Saylor] 12.2, "The Arrangement of Atoms in Crystalline Solids." [JS] 3.1, "Seven Systems and Fourteen Lattices." [JS] 3.2, "Metal Structures." |
Lecture 15: Introduction to Crystallography (00:52:51) Lecture 15: Introduction to Crystallography > Download from iTunes U (MP4 - 225MB) > Download from Internet Archive (MP4 - 225MB) |
› Textbook Problems |
› Supplemental Readings Hooke, Robert. Micrographia; or, Some Physiological Descriptions of Minute Bodies Made by Magnifying Glasses, with Observations and Inquiries. London, England: J. Martyn and J. Allestry, 1665. [View on Project Gutenberg] Chapman, Allan. England's Leonardo: Robert Hooke and the Seventeenth-Century Scientific Revolution. Philadelphia, PA: Institute of Physics Publishing, 2005. ISBN: 9780750309875. Steno, Nicolaus. The Prodromus of Nicolaus Steno's Dissertation Concerning a Solid Body Enclosed by Process of Nature within a Solid. Translated by John Garrett Winter. New York, NY: Macmillan, 1916. Cutler, Alan. The Seashell on the Mountaintop: A Story of Science, Sainthood, and the Humble Genius Who Discovered a New History of the Earth. New York, NY: Plume, 2004. ISBN: 9780452285460. Dijksterhuis, Fokko Jan. Lenses and Waves: Christiaan Huygens and the Mathematical Science of Optics in the Seventeenth Century. Boston, MA: Kluwer, 2004. ISBN: 9789048167067. › People Auguste Bravais; René Just Haüy; Robert Hooke; Christiaan Huygens; Niels Steensen (Nicolaus Steno) › Culture Vallier, Dora. Braque: The Complete Graphics: Catalogue Raisonne. New York, NY: Alpine Fine Arts Collection, 1988. ISBN: 9780881680065. Talking Heads. "Burning Down the House." Speaking in Tongues. Sire Records, 1983. › Other OCW and OER Content
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Crystallographic Notation & X-Rays |
› Readings Archived Lecture Notes #4 (PDF), Section 4 Archived Lecture Notes #5 (PDF), Section 1 [Saylor] 12.2, "The Arrangement of Atoms in Crystalline Solids." [JS] 3.2, "Metal Structures." [JS] 3.6, "Lattice Positions, Directions, and Planes." |
Lecture 16: Crystallographic Notation & X-Rays (00:45:44) Lecture 16: Crystallographic Notation & X-Rays > Download from iTunes U (MP4 - 194MB) > Download from Internet Archive (MP4 - 194MB) |
Lecture Slides (PDF) |
› Textbook Problems [JS] Chapter 3, Sample Problems 8-10, 13-19; Practice Problems 11-14, 16-21 |
› Supplemental Readings Thomas, A. M. K. The Invisible Light: 100 Years of Medical Radiology. Cambridge, MA: Wiley-Blackwell, 1995. ISBN: 9780865426276. › People › Other OCW and OER Content |
X-Ray Emission & Absorption |
› Readings Archived Lecture Notes #5 (PDF), Section 2 [Saylor] 7.1, "The Role of Atomic Number in the Periodic Table." (only read until Example 1) [C&S] 1, "Properties of X-Rays." |
Lecture 17: X-Ray Emission & Absorption (00:51:15) Lecture 17: X-Ray Emission & Absorption > Download from iTunes U (MP4 - 218MB) > Download from Internet Archive (MP4 - 218MB) |
Lecture Slides (PDF - 3.5MB) |
› Textbook Problems [Saylor] 12.3, "Structures of Simple Binary Compounds." |
› Supplemental Readings Moseley, H. G. J. "The High-Frequency Spectra of the Elements." Philosophical Magazine Series 6 26 (December 1913): 1024-1034. Heilbron, John Lewis. H. G. J. Moseley: The Life and Letters of an English Physicist, 1887-1915. Berkeley, CA: University of California Press, 1974. ISBN: 9780520023758. › People › Culture Bacou, Roseline. Millet: One Hundred Drawings. New York, NY: Harper & Row, 1975. ISBN: 9780064303408. Lubar, Robert S. Dali: The Salvador Dali Museum Collection. Boston, MA: Bullfinch Press, 2000. ISBN: 9780821227152. › Other OCW and OER Content |
X-Ray Diffraction Techniques |
› Readings Archived Lecture Notes #5 (PDF), Sections 4-6 [Saylor] 12.3, "Structures of Simple Binary Compounds." [JS] 3.7, "X-Ray Diffraction." |
Lecture 18: X-Ray Diffraction Techniques (00:45:28) Lecture 18: X-Ray Diffraction Techniques > Download from iTunes U (MP4 - 194MB) > Download from Internet Archive (MP4 - 194MB) |
› Textbook Problems |
› People William Henry Bragg, William Lawrence Bragg – 1915 Nobel Prize in Physics; Max von Laue – 1914 Nobel Prize in Physics; Dan Shechtman; Roger Penrose; Peter Debye – 1936 Nobel Prize in Chemistry; Paul Scherrer › Culture Mozart, Wolfgang. "Rondo Alla Turca." Piano Sonata no. 11 in A major, K. 331. Other OCW and OER Content |
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Point & Line Defects |
› Readings Archived Lecture Notes #6 (PDF), Sections 1-2 [Saylor] 12.4, "Defects in Crystals." [JS] 4.1, "The Solid Solution – Chemical Imperfection." [JS] 4.2, "Point Defects – Zero-Dimensional Imperfections." [JS] 4.3, "Linear Defects, or Dislocations – One-Dimensional Imperfections." [JS] 5.1, "Thermally-Activated Processes." [JS] 5.2, "Thermal Production of Point Defects." |
Lecture 19: Point & Line Defects (00:49:21) |
› Textbook Problems |
› Supplemental Readings Hull, Derek, and David J. Bacon. Introduction to Dislocations. Boston, MA: Butterworth-Heinemann, 2001. ISBN: 9780750646819. › People › Culture › Other OCW and OER Content |
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Line, Interface & Bulk Defects |
› Readings Archived Lecture Notes #6 (PDF), Sections 3-4 [Saylor] 12.4, "Defects in Crystals." [JS] 4.3, "Linear Defects, or Dislocations – One-Dimensional Imperfections." [JS] 4.4, "Planar Defects – Two-Dimensional Imperfections." |
Lecture 20: Line, Interface & Bulk Defects (00:48:11) Lecture 20: Line, Interface & Bulk Defects > Download from iTunes U (MP4 - 205MB) > Download from Internet Archive (MP4 - 205MB) |
Lecture Slides (PDF) |
› Textbook Problems [Saylor] 12.4, "Defects in Crystals." |
› Supplemental Readings Hull, Derek, and David J. Bacon. Introduction to Dislocations. Boston, MA: Butterworth-Heinemann, 2001. ISBN: 9780750646819. › People › Culture Glass, Philip. Koyaanisqatsi. Orange Mountain Music, 2009. Horner, James, and Will Jennings. "My Heart Will Go On (Theme from Titanic)." Titanic: Music from the Motion Picture. Performed by Celine Dion. Columbia Records, 1997. › Other OCW and OER Content |
Self-Assessment: Crystalline Materials
SCOPE | WEEKLY QUIZ | EXAM PROBLEMS | EXAM HELP SESSION VIDEOS | SUPPLEMENTAL PROBLEMS |
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Crystalline Materials | Quiz Solutions Key (PDF) | Exam Solutions Key (PDF - 1.5MB) |
› Video Clips
Clip 1: Exam 2, Problem 1 (00:23:00)
Clip 1: Exam 2, Problem 1 > Download from iTunes U (MP4 - 52MB) > Download from Internet Archive (MP4 - 52MB) Clip 2: Exam 2, Problem 2 > Download from iTunes U (MP4 - 60MB) > Download from Internet Archive (MP4 - 60MB) Clip 3: Exam 3, Problem 1 > Download from iTunes U (MP4 - 36MB) > Download from Internet Archive (MP4 - 36MB) |
Supplemental Exam Problems (PDF) Supplemental Exam Solutions Key (PDF - 1.1MB) |
Amorphous Materials
TITLES | READINGS | LECTURE VIDEOS | LECTURE RESOURCES | HOMEWORK | FOR FURTHER STUDY |
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Introduction to Glasses |
› Readings Archived Lecture Notes #7 (PDF) [JS] 4.5, "Noncrystalline Solids – Three-Dimensional Imperfections." [JS] 12.2, "Glasses – Noncrystalline Materials." |
Lecture 21: Introduction to Glasses (00:47:51) | Lecture Slides (PDF) |
› Supplemental Readings Stookey, Stanley Donald. The Hydrogen-Lead, Hydrogen-Palladium, and Deuterium-Palladium Equilibria. Ph. D. thesis, Massachusetts Institute of Technology, 1940. Chang, Kenneth. "The Nature of Glass Remains Anything But Clear." New York Times, July 29, 2008. › Culture Kuspit, Donald B. Chihuly. New York, NY: Harry N. Abrams, 1999. ISBN: 9780810963733. Chihuly, Dale. Chihuly: Form From Fire. Seattle, WA: University of Washington Press, 1993. ISBN: 9780933053069. › Other OCW and OER Content |
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Engineering Glass Properties; Introduction to Kinetics |
› Readings Archived Lecture Notes #7 (PDF) Archived Lecture Notes #8 (PDF) [Saylor] 14.5, "Half-Lives and Radioactive Decay Kinetics." [Saylor] 14.6, "Reaction Rates – A Microscopic View." [Saylor] 14.7, "The Collision Model of Chemical Kinetics." [JS] 12.2, "Glasses – Noncrystalline Materials." [JS] 12.3, "Glass-Ceramics." |
Lecture 22: Engineering Glass Properties, Introduction to Kinetics (00:52:40) Lecture 22: Engineering Glass Properties, Introduction to Kinetics > Download from iTunes U (MP4 - 224MB) > Download from Internet Archive (MP4 - 224MB) |
› Homework › Textbook Problems |
› Supplemental Readings Libby, Willard F. Radiocarbon Dating. Chicago, IL: University of Chicago Press, 1969. › People › Culture Chambers, Joe, and Willie Chambers. "Time Has Come Today." The Time Has Come. Performed by The Chambers Brothers. Columbia Records, 1967. › Other OCW and OER Content |
Self-Assessment: Amorphous Materials
SCOPE | WEEKLY QUIZ | EXAM PROBLEMS | EXAM HELP SESSION VIDEOS | SUPPLEMENTAL PROBLEMS |
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Amorphous Materials | Quiz Solutions Key (PDF) | Exam Solutions Key (PDF) | Clip 1: Exam 3, Problem 2A (00:04:00) |
Supplemental Exam Problems (PDF) Supplemental Exam Solutions Key (PDF) |
Reactions and Kinetics
TITLES | READINGS | LECTURE VIDEOS | LECTURE RESOURCES | HOMEWORK | FOR FURTHER STUDY |
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Reaction Rates |
› Readings Archived Lecture Notes #8 (PDF), Sections 4-7 Archived Lecture Notes #9 (PDF), Section 1 [Saylor] 10.7, "The Kinetic Molecular Theory of Gases." [Saylor] 14.1, "Factors That Affect Reaction Rates." [Saylor] 14.2, "Reaction Rates and Rate Laws." [Saylor] 14.3, "Methods of Determining Reaction Orders."[Saylor] 14.4, "Using Graphs to Determine Rate Laws, Rate Constants, and Reaction Orders." [JS] 5.1, "Thermally Activated Processes." [JS] 5.2, "Thermal Production of Point Defects." |
Lecture 23: Reaction Rates (00:52:49) |
› Homework Problems |
› Supplemental Readings Fick, Adolf. "Ueber Diffusion." Annalen der Physik 170 (1855): 59-86. (Note: this article is in German.) › People › Culture Lauper, Cyndi, and Rob Hyman. "Time After Time." She's So Unusual. Performed by Cyndi Lauper. Epic Records, 1984. Lennon, John, and Paul McCartney. "Baby You Can Drive My Car." Rubber Soul. Performed by The Beatles. EMI, 1965. › Other OCW and OER Content |
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Diffusion |
› Readings Archived Lecture Notes #9 (PDF) [JS] 5.2, "Thermal Production of Point Defects." [JS] 5.3, "Point Defects and Solid-State Diffusion." [JS] 5.4, "Steady-State Diffusion." [JS] 5.5, "Alternate Diffusion Paths." |
Lecture 24: Diffusion (00:50:49) |
› Supplemental Readings Fick, Adolf. "Ueber Diffusion." Annalen der Physik 170 (1855): 59-86. (Note: this article is in German.) Carslaw, Horatio S., and John C. Jaeger. Conduction of Heat in Solids. Oxford, England: Clarendon Press, 2004. ISBN: 9780198533689. › People › Culture Wagner, Richard. "Ride of the Valkyries." Die Walküre, WWV 86B. Hornsby, Bruce, and John Hornsby. "The Way It Is." The Way It Is. Performed by Bruce Hornsby and the Range. RCA, 1986. › Other OCW and OER Content |
Self-Assessment: Reactions and Kinetics
SCOPE | WEEKLY QUIZ | EXAM PROBLEMS | EXAM HELP SESSION VIDEOS | SUPPLEMENTAL PROBLEMS |
---|---|---|---|---|
Reactions and Kinetics | Quiz Solutions Key (PDF) | Exam Solutions Key (PDF) |
› Video Clips
Clip 1: Exam 3, Problem 4 (00:14:00)
Clip 1: Exam 3, Problem 4 > Download from iTunes U (MP4 - 32MB) > Download from Internet Archive (MP4 - 32MB) Clip 2: Exam 3, Problem 5 > Download from iTunes U (MP4 - 32MB) > Download from Internet Archive (MP4 - 32MB) |
Supplemental Exam Problems (PDF) Supplemental Exam Solutions Key (PDF) |
Aqueous Solutions
TITLES | READINGS | LECTURE VIDEOS | LECTURE RESOURCES | HOMEWORK | FOR FURTHER STUDY |
---|---|---|---|---|---|
Introduction to Aqueous Solutions |
› Readings |
Lecture 25: Introduction to Aqueous Solutions (00:50:42) Lecture 25: Introduction to Aqueous Solutions > Download from iTunes U (MP4 - 216MB) > Download from Internet Archive (MP4 - 216MB) |
› Textbook Problems [Saylor] 17.1, "Determining the Solubility of Ionic Compounds." |
› Supplemental Readings Chang, Kenneth. "The Nature of Glass Remains Anything but Clear." The New York Times, July 29, 2008. › People |
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Acids & Bases |
› Readings [Saylor] 4.6, "Acid-Base Reactions." [Saylor] 8.7, "Lewis Acids and Bases." [Saylor] 16.1, "The Autoionization of Water." [Saylor] 16.2, "A Qualitative Description of Acid-Base Equilibria." [Saylor] 16.3, "Molecular Structure and Acid-Base Strength." [Saylor] 16.4, "Quantitative Aspects of Acid-Base Equilibria." |
Lecture 26: Acids & Bases (00:52:37) |
› Textbook Problems |
› Supplemental Readings Djerassi, C., and R. Hoffmann. Oxygen: A Play in Two Acts. New York, NY: Wiley-VCH, 2001. ISBN: 9783527304134. See also the study guide and other publisher resources. Brandis, Kerry. Acid-Base Physiology. See Chapter 1 of this online tutorial/textbook, which applies acid-base chemistry to physiology. › People Antoine Lavoisier; Svante Arrhenius — 1903 Nobel Prize in Chemistry; Johannes Nicolaus Brønsted; Martin Lowry; Gilbert N. Lewis › Other OCW and OER Content |
Self-Assessment: Aqueous Solutions
SCOPE | WEEKLY QUIZ | EXAM PROBLEMS | EXAM HELP SESSION VIDEOS | SUPPLEMENTAL PROBLEMS |
---|---|---|---|---|
Aqueous Solutions | Quiz Solutions Key (PDF) | Exam Solutions Key (PDF) |
Clip 1: Exam 3, Problem 3 (00:13:00) Clip 1: Exam 3, Problem 3 > Download from iTunes U (MP4 - 29MB) > Download from Internet Archive (MP4 - 29MB) |
Supplemental Exam Problems (PDF) Supplemental Exam Solutions Key (PDF) |
Organic Materials
TITLES | READINGS | LECTURE VIDEOS | LECTURE RESOURCES | HOMEWORK | FOR FURTHER STUDY |
---|---|---|---|---|---|
Introduction to Organic Chemistry |
› Readings |
Lecture 27: Introduction to Organic Chemistry (00:52:09) Lecture 27: Introduction to Organic Chemistry > Download from iTunes U (MP4 - 222MB) > Download from Internet Archive (MP4 - 222MB) |
Lecture Slides (PDF - 1.6MB) | None |
› People › Other OCW and OER Content |
Polymers: Structure & Composition |
› Readings
[Saylor] 12.8, "Polymeric Solids."
|
Lecture 28: Polymers: Structure & Composition (00:48:46) Lecture 28: Polymers: Structure & Composition > Download from iTunes U (MP4 - 207MB) > Download from Internet Archive (MP4 - 207MB) |
Lecture Slides (PDF) |
› Textbook Problems |
› Culture The Beatles. "Polythene Pam." Abbey Road. Apple Records, 1969. › Other OCW and OER Content |
Polymers: Synthesis, Properties & Applications |
› Readings |
Lecture 29: Polymers: Synthesis, Properties & Applications (00:48:50) Lecture 29: Polymers: Synthesis, Properties & Applications > Download from iTunes U (MP4 - 207MB) > Download from Internet Archive (MP4 - 207MB) |
› Textbook Problems [JS] Chapter 13, Sample Problems 13.1 and 13.4 |
› Supplemental Readings Perree, R. Bakelite: The Material of a Thousand Uses. Amsterdam, NL: Cadre, 1996. ISBN: 9789053492338. Meikle, J. American Plastic: A Culture History. New Brunswick, NJ: Rutgers University Press, 1995. ISBN: 9780813522357. Brown, D. E. Inventing Modern America: From the Microwave to the Mouse. Cambridge, MA: MIT Press, 2001. ISBN: 9780262523493. [Companion website] Carothers, W.H. Collected Papers of Wallace Hume Carothers on High Polymeric Substances. New York, NY: Interscience Publishers, 1940. ISBN: 9781406759259. [Download or view complete work from Internet Archive] Furukawa, Y. Inventing Polymer Science: Staudinger, Carothers, and the Emergence of Macromolecular Science. Philadelphia, PA: University of Pennsylvania Press, 1998. ISBN: 9780812233360. › People › Culture "Mr. Cellophane." Chicago. DVD. Miramax, 2003. The Graduate. Directed by M. Nichols. DVD. MGM, 1967. › Other OCW and OER Content |
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Biochemistry: Amino Acids |
› Readings |
Lecture 30: Biochemistry: Amino Acids (00:51:20) Lecture 30: Biochemistry: Amino Acids > Download from iTunes U (MP4 - 218MB) > Download from Internet Archive (MP4 - 218MB) |
› Textbook Problems [Saylor] 12.8, "Polymeric Solids." |
› Supplemental Readings › Culture Michael Jackson. "Man in the Mirror." Bad. Epic Records, 1987. › Other OCW and OER Content |
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Biochemistry: Protein Structure |
› Readings [PB-EOC] 17-6 through 17-12 in Chapter 17, "Amino Acids, Peptides, and Proteins." |
Lecture 31: Biochemistry: Protein Structure (00:50:38) Lecture 31: Biochemistry: Protein Structure > Download from iTunes U (MP4 - 216MB) > Download from Internet Archive (MP4 - 216MB) |
› Other OCW and OER Content |
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Biochemistry: Lipids, Nucleic Acids & DNA |
› Readings |
Lecture 32: Biochemistry: Lipids, Nucleic Acids & DNA (00:51:25) Lecture 32: Biochemistry: Lipids, Nucleic Acids & DNA > Download from iTunes U (MP4 - 217MB) > Download from Internet Archive (MP4 - 217MB) |
› Supplemental Readings Watson, J. D., and F. H. C. Crick. "Molecular Structure of Nucleic Acids." Nature 171 (1953): 737-738. (PDF) Franklin, R., and R. G. Gosling. "Molecular Configuration in Sodium Thymonucleate." Nature 171 (1953): 740-741. (PDF) Judson, Horace Freeland. The Eighth Day of Creation: Makers of the Revolution in Biology. 25th anniversary edition. Woodbury, NY: Cold Spring Harbor Laboratory Press, 1996. ISBN: 9780879694784. Maddox, Brenda. Rosalind Franklin: The Dark Lady of DNA. New York, NY: HarperCollins, 2002. ISBN: 9780060184070. Watson, James D. The Double Helix: A Personal Account of the Discovery of the Structure of DNA. New York, NY: Touchstone/Simon & Schuster, 2001 (original publication 1968). ISBN: 9780743216302. › People Oswald Avery; Erwin Chargaff; Francis Crick, James Watson, Maurice Wilkins — 1962 Nobel Prize in Physiology or Medicine; Rosalind Franklin › Culture "It's a Chemical Reaction, That's All." Music and lyrics by Cole Porter. From Silk Stockings. Fred Astaire, Cyd Charisse; directed by Rouben Mamoulian and Roy Mack. Original film release MGM, 1957. DVD, Warner Home Video, 2003. Hank Ballard and the Midnighters. "The Twist." (B-side with "Teardrops on Your Letter.") Original release: King Records, 1959. Available on many reissue compilations, such as Their Very Best: Hank Ballard & The Midnighters. K-Tel, 2007. › Other OCW and OER Content |
Self-Assessment: Organic Materials
SCOPE | WEEKLY QUIZ | EXAM PROBLEMS | EXAM HELP SESSION VIDEOS | SUPPLEMENTAL PROBLEMS |
---|---|---|---|---|
Organic Materials | Quiz Solutions Key (PDF) | Exam Solutions Key (PDF) |
Clip 1: Final Exam, Problem 5 (00:20:00) Clip 1: Final Exam, Problem 5 > Download from iTunes U (MP4 - 44MB) > Download from Internet Archive (MP4 - 44MB) |
Solid Solutions
TITLES | READINGS | LECTURE VIDEOS | LECTURE RESOURCES | HOMEWORK | FOR FURTHER STUDY |
---|---|---|---|---|---|
Unary Phase Diagrams |
› Readings Archived Lecture Notes #10 (PDF), Part A [Saylor] 11.6, "Critical Temperature and Pressure." [Saylor] 11.7, "Phase Diagrams." |
Lecture 33: Unary Phase Diagrams (00:51:21) | Lecture Slides (PDF - 3.0MB) |
› Culture Queen. "'Under Pressure' (Live at Wembley)." June 16, 2009. YouTube. Accessed November 18, 2010. http://www.youtube.com/watch?v=SJCTgtDU-74. Alexander Calder, Mercury Fountain, 1937. Fundació Joan Miró. Barcelona, Spain. › Other OCW and OER Content |
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Binary Phase Diagrams: Complete Solubility |
› Readings Archived Lecture Notes #10 (PDF), Part B and #10 Supplement (PDF) [JS] 9.1, "The Phase Rule." [JS] 9.2, "The Phase Diagram." |
Lecture 34: Binary Phase Diagrams: Complete Solubility (00:49:33) Lecture 34: Binary Phase Diagrams: Complete Solubility > Download from iTunes U (MP4 - 210MB) > Download from Internet Archive (MP4 - 210MB) |
Lecture Slides (PDF - 2.5MB) |
› Supplemental Readings Carter, Kelley. "Absinthe flows again, more stylish than ever." USA Today, September 27, 2007. › People › Culture The Manchurian Candidate. Directed by John Frankenheimer. MGM, 1962. Moulin Rouge! Directed by Baz Luhrmann. 20th Century Fox, 2001. › Other OCW and OER Content |
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Binary Phase Diagrams: Limited Solubility |
› Readings Archived Lecture Notes #10 (PDF), Part B and #10 Supplement (PDF) [JS] 9.1, "The Phase Rule." [JS] 9.2, "The Phase Diagram." |
Lecture 35: Binary Phase Diagrams: Limited Solubility (00:47:58) Lecture 35: Binary Phase Diagrams: Limited Solubility > Download from iTunes U (MP4 - 203MB) > Download from Internet Archive (MP4 - 203MB) |
› People Daniel Fahrenheit; Nicole Barbe Ponsardin (Madame Ponsardin Cliquot) › Other OCW and OER Content |
Self-Assessment: Solid Solutions
SCOPE | WEEKLY QUIZ | EXAM PROBLEMS | EXAM HELP SESSION VIDEOS | SUPPLEMENTAL PROBLEMS |
---|---|---|---|---|
Solid Solutions | Quiz Solutions Key (PDF) | Exam Solutions Key (PDF) |
Clip 1: Final Exam, Problem 7 (00:13:00) Clip 1: Final Exam, Problem 7 > Download from iTunes U (MP4 - 29MB) > Download from Internet Archive (MP4 - 29MB) |
Final Exam
FINAL EXAM | STUDY MATERIALS | FINAL EXAM AND SOLUTIONS |
---|---|---|
Final Exam | Lecture Summary Notes (PDF - 4.8MB) |
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