1 00:00:15,915 --> 00:00:19,118 This is a great time for me to tell you 2 00:00:19,118 --> 00:00:21,220 about my why this matters. 3 00:00:21,220 --> 00:00:23,522 And, of course, the sp2 carbon atom 4 00:00:23,522 --> 00:00:30,129 matters because of drinking water, of course. 5 00:00:30,129 --> 00:00:31,730 And, you know, this is a well-- 6 00:00:31,730 --> 00:00:35,267 in a district in India where more than 50% of the wells 7 00:00:35,267 --> 00:00:37,636 exceed the WHO limits for arsenic 8 00:00:37,636 --> 00:00:41,640 by around a factor of 5. 9 00:00:41,640 --> 00:00:44,743 1.8 billion people in the world drink fecally contaminated 10 00:00:44,743 --> 00:00:46,378 water on a daily basis. 11 00:00:46,378 --> 00:00:50,349 600 million people boil their water in the world. 12 00:00:50,349 --> 00:00:52,117 Boiling doesn't help with arsenic, though, 13 00:00:52,117 --> 00:00:54,520 arsenic just stays in the boiled water. 14 00:00:54,520 --> 00:00:57,723 It kills bacteria, but it doesn't help with toxic-- 15 00:00:57,723 --> 00:01:00,192 toxic elements. 16 00:01:00,192 --> 00:01:02,294 If you look at the world as a whole, 17 00:01:02,294 --> 00:01:06,532 and you look at sort of where there are water-- 18 00:01:06,532 --> 00:01:10,402 water crisis, where the water crisis is at this level, 19 00:01:10,402 --> 00:01:14,940 it's a little over 3 and 1/2 billion people. 20 00:01:14,940 --> 00:01:20,079 And in those countries, almost 185 or so countries, 21 00:01:20,079 --> 00:01:22,381 where this is a serious problem, if you 22 00:01:22,381 --> 00:01:27,119 look at the cost of disease, and the cause of death 23 00:01:27,119 --> 00:01:31,323 in those countries, 70% to 80% of all disease and almost 30% 24 00:01:31,323 --> 00:01:34,493 of all death can be attributed to the water quality. 25 00:01:34,493 --> 00:01:35,194 Right. 26 00:01:35,194 --> 00:01:38,330 So when I talk about water as a problem, 27 00:01:38,330 --> 00:01:40,966 I really mean it's a serious problem. 28 00:01:40,966 --> 00:01:43,936 It's a problem of life or death. 29 00:01:43,936 --> 00:01:47,439 Now, this is-- to get fresh drinking water, 30 00:01:47,439 --> 00:01:50,009 if you look at the planet, and you say, well, where 31 00:01:50,009 --> 00:01:51,710 is the water on this planet? 32 00:01:51,710 --> 00:01:54,346 Where is the water on this planet? 33 00:01:54,346 --> 00:02:01,520 I like this picture because we consume water volumetrically, 34 00:02:01,520 --> 00:02:03,155 not in an area, right? 35 00:02:03,155 --> 00:02:05,724 We use water as a volume, and this 36 00:02:05,724 --> 00:02:10,596 is the water we have on this precious planet as a volume. 37 00:02:10,596 --> 00:02:14,366 This bubble here is all of the ocean water. 38 00:02:14,366 --> 00:02:17,503 It's about 70-- it's about 97% of all the water. 39 00:02:17,503 --> 00:02:21,974 That bubble there is freshwater that is inaccessible. 40 00:02:21,974 --> 00:02:22,808 It's frozen. 41 00:02:22,808 --> 00:02:24,576 And this one here, you can't really see it, 42 00:02:24,576 --> 00:02:26,311 there is another dot there. 43 00:02:26,311 --> 00:02:28,579 That's less than 1% of the world's water. 44 00:02:28,579 --> 00:02:31,016 That is our drinking water ecosystem 45 00:02:31,016 --> 00:02:34,319 that is what we are destroying. 46 00:02:34,319 --> 00:02:35,554 And-- so what-- 47 00:02:35,554 --> 00:02:36,055 OK. 48 00:02:36,055 --> 00:02:40,292 So there's a lot of things we can try to do about this. 49 00:02:40,292 --> 00:02:41,727 One of the things we can try to do 50 00:02:41,727 --> 00:02:44,228 is to see if we can tap into this 51 00:02:44,228 --> 00:02:47,466 in a way that's more affordable and more efficient. 52 00:02:47,466 --> 00:02:51,770 Because there's a lot of water here, right, and use that. 53 00:02:51,770 --> 00:02:54,840 But the problem is, if you look at the cost of desalination 54 00:02:54,840 --> 00:02:58,043 today as opposed to the cost-- that's desalination. 55 00:02:58,043 --> 00:02:59,411 If you look at the cost as opposed 56 00:02:59,411 --> 00:03:01,613 to just digging water out of a well, 57 00:03:01,613 --> 00:03:03,282 like the one I just showed you in India, 58 00:03:03,282 --> 00:03:05,317 it's over a factor of 10. 59 00:03:05,317 --> 00:03:06,085 Still. 60 00:03:06,085 --> 00:03:09,353 And, in fact, one of the big issues with desalination 61 00:03:09,353 --> 00:03:12,858 isn't just the total cost or the operating costs, 62 00:03:12,858 --> 00:03:13,926 but the capital cost. 63 00:03:13,926 --> 00:03:18,097 How do you build this plant in the first place? 64 00:03:18,097 --> 00:03:22,901 And so it takes too much money. 65 00:03:22,901 --> 00:03:26,572 If you look at the thing that's at the heart of desalination, 66 00:03:26,572 --> 00:03:28,373 it's a filter, right. 67 00:03:28,373 --> 00:03:28,974 It's a filter. 68 00:03:28,974 --> 00:03:30,409 And I talked about this in my last, 69 00:03:30,409 --> 00:03:33,212 why this matters, when I talk about separations, 70 00:03:33,212 --> 00:03:35,380 and I promised that in my next why does this matter, 71 00:03:35,380 --> 00:03:36,915 I'd talk about water. 72 00:03:36,915 --> 00:03:37,449 Right. 73 00:03:37,449 --> 00:03:39,118 Which is what I'm doing. 74 00:03:39,118 --> 00:03:40,552 If you look at a desal plant, this 75 00:03:40,552 --> 00:03:42,754 is one of the world's largest, this is a plant called 76 00:03:42,754 --> 00:03:44,890 the Hadera plant in Israel, and you 77 00:03:44,890 --> 00:03:46,758 look at what their costs are that-- remember, 78 00:03:46,758 --> 00:03:49,361 the costs digits-- half of that cost-- almost half of the cost 79 00:03:49,361 --> 00:03:51,029 isn't just energy. 80 00:03:51,029 --> 00:03:54,466 And almost all of that energy is in pushing salt water 81 00:03:54,466 --> 00:03:56,034 through a filter. 82 00:03:56,034 --> 00:03:58,137 Through a membrane. 83 00:03:58,137 --> 00:04:00,072 That's called a reverse osmosis membrane, 84 00:04:00,072 --> 00:04:04,009 because you're going against the osmotic pressure. 85 00:04:04,009 --> 00:04:06,578 And if you look at the membrane itself-- 86 00:04:06,578 --> 00:04:08,147 this is a picture of it, it's actually 87 00:04:08,147 --> 00:04:11,984 a very small layer on top of this active layer that 88 00:04:11,984 --> 00:04:13,385 does all the work-- 89 00:04:13,385 --> 00:04:15,721 it's not a very good design. 90 00:04:15,721 --> 00:04:20,358 In fact, membranes for desalination are pretty bad. 91 00:04:20,358 --> 00:04:21,493 Right. 92 00:04:21,493 --> 00:04:24,163 They kind of do everything worse than they should, 93 00:04:24,163 --> 00:04:27,499 except that they work, which is good, and they're cheap, 94 00:04:27,499 --> 00:04:28,767 $1.00 a square foot. 95 00:04:28,767 --> 00:04:30,969 But, see, they're very-- they take much more energy 96 00:04:30,969 --> 00:04:32,938 than you need. 97 00:04:32,938 --> 00:04:35,007 They foul up very easily. 98 00:04:35,007 --> 00:04:37,409 And then that means stuff gets kind of, you know, 99 00:04:37,409 --> 00:04:38,944 stuck in them. 100 00:04:38,944 --> 00:04:42,347 And then you can't take it-- you can't clean them 101 00:04:42,347 --> 00:04:45,017 because these polyamide membranes, which 102 00:04:45,017 --> 00:04:47,753 are the same polymer used in these membranes for 50 years, 103 00:04:47,753 --> 00:04:50,856 haven't changed, the material. 104 00:04:50,856 --> 00:04:53,325 Those polyamide membranes are destroyed by chlorine. 105 00:04:53,325 --> 00:04:56,528 So even in a desal plant-- in a desal plant, 106 00:04:56,528 --> 00:05:00,299 if you have drinking water in your feed stream, 107 00:05:00,299 --> 00:05:02,534 drinking water has six parts per million chlorine. 108 00:05:02,534 --> 00:05:03,769 That's not much. 109 00:05:03,769 --> 00:05:07,539 They still will go through the cost to remove it. 110 00:05:07,539 --> 00:05:08,907 They will remove it from the feed. 111 00:05:08,907 --> 00:05:09,441 Why? 112 00:05:09,441 --> 00:05:12,077 Because if you leave that little amount of chlorine in the feed, 113 00:05:12,077 --> 00:05:13,312 these membranes get destroyed. 114 00:05:13,312 --> 00:05:16,315 By the way, there's 40,000 of these membranes in this plant. 115 00:05:16,315 --> 00:05:20,085 Each one is 2 meters long and 40 square meters of area. 116 00:05:20,085 --> 00:05:24,556 So-- so these are so delicate that you can't really 117 00:05:24,556 --> 00:05:26,091 clean them well. 118 00:05:26,091 --> 00:05:28,927 And that's part of what the cost of a plant involves. 119 00:05:28,927 --> 00:05:31,029 That's part of what the cost of a plant involves. 120 00:05:31,029 --> 00:05:33,065 Now, this would be like a plant, right, you 121 00:05:33,065 --> 00:05:36,401 have sea water coming in and, you know-- and then 122 00:05:36,401 --> 00:05:38,270 you've got your membrane module that's taking 123 00:05:38,270 --> 00:05:40,072 the salt out of the water. 124 00:05:40,072 --> 00:05:41,206 And then the product water. 125 00:05:41,206 --> 00:05:44,876 But because this filter is so delicate-- 126 00:05:44,876 --> 00:05:46,044 there's the picture-- 127 00:05:46,044 --> 00:05:47,512 because that filter is so delicate, 128 00:05:47,512 --> 00:05:50,082 you actually have to add a whole lot more to the plant. 129 00:05:50,082 --> 00:05:53,318 So much of a desal plant is built around essentially 130 00:05:53,318 --> 00:05:55,954 protecting this membrane. 131 00:05:55,954 --> 00:05:57,055 So that's cost. 132 00:05:57,055 --> 00:05:58,757 That's cost. 133 00:05:58,757 --> 00:05:59,258 Right. 134 00:05:59,258 --> 00:06:01,860 A better membrane could change this. 135 00:06:01,860 --> 00:06:04,162 But like I said, the membrane-- oh, there it is. 136 00:06:04,162 --> 00:06:07,833 You can't Snapchat on that. 137 00:06:07,833 --> 00:06:08,433 Snapchat? 138 00:06:08,433 --> 00:06:10,035 What is it that people do today? 139 00:06:10,035 --> 00:06:10,802 Not Snapchat. 140 00:06:10,802 --> 00:06:11,570 Yeah, Snapchat. 141 00:06:11,570 --> 00:06:12,070 Yeah. 142 00:06:12,070 --> 00:06:12,571 OK. 143 00:06:12,571 --> 00:06:13,405 Thank you. 144 00:06:13,405 --> 00:06:14,673 You can't Snapchat on that. 145 00:06:14,673 --> 00:06:17,276 That's what I meant. 146 00:06:17,276 --> 00:06:19,478 I know it's not My Space, but I don't know-- 147 00:06:19,478 --> 00:06:25,584 but, anyway, this is like even-- you know, when I look at-- 148 00:06:25,584 --> 00:06:28,387 at membranes today as a material scientist and materials 149 00:06:28,387 --> 00:06:30,389 chemists, all of your membranes, I think, 150 00:06:30,389 --> 00:06:31,990 that's what it looks like. 151 00:06:31,990 --> 00:06:32,591 Why? 152 00:06:32,591 --> 00:06:33,759 Doesn't have to be the case. 153 00:06:33,759 --> 00:06:36,228 We can do so much better. 154 00:06:36,228 --> 00:06:37,296 And so-- OK. 155 00:06:37,296 --> 00:06:39,464 Energy costs goes into pretreatment, secondary 156 00:06:39,464 --> 00:06:41,933 treatment, and this is where this comes back. 157 00:06:41,933 --> 00:06:46,972 This beautiful material that we have now understood more 158 00:06:46,972 --> 00:06:47,906 than we did before. 159 00:06:47,906 --> 00:06:49,841 Because, remember, before I showed 160 00:06:49,841 --> 00:06:51,476 you graphene and I showed you-- 161 00:06:51,476 --> 00:06:52,511 no, I showed you benzene. 162 00:06:55,013 --> 00:06:57,582 And we talked about it as a Lewis resonant structure, 163 00:06:57,582 --> 00:06:58,283 remember? 164 00:06:58,283 --> 00:06:58,784 Right. 165 00:06:58,784 --> 00:07:02,020 A Lewis resonant structure to help explain how it looked. 166 00:07:02,020 --> 00:07:06,458 You know, gra-- graphene does not have alternating bonds. 167 00:07:06,458 --> 00:07:08,593 Remember, that's what we talked about before. 168 00:07:08,593 --> 00:07:11,396 It's a Lewis resonant structure. 169 00:07:11,396 --> 00:07:13,532 So it lowers its energy by having 170 00:07:13,532 --> 00:07:17,936 two sets of structures that have sort of alternating bonds. 171 00:07:17,936 --> 00:07:19,938 We talked about it in the context of benzene. 172 00:07:19,938 --> 00:07:22,974 But, see, now you know so much more. 173 00:07:22,974 --> 00:07:24,209 You know so much more. 174 00:07:24,209 --> 00:07:28,246 Because, now, you know why graphene is so special. 175 00:07:28,246 --> 00:07:30,248 You know why graphene is so special. 176 00:07:30,248 --> 00:07:33,518 It actually is the hybridization. 177 00:07:33,518 --> 00:07:34,519 It's the hybridization. 178 00:07:34,519 --> 00:07:37,289 Because on top, and on the bottom, 179 00:07:37,289 --> 00:07:41,693 of a single atom of a single sheet of graphene, 180 00:07:41,693 --> 00:07:44,763 you've got pi bonding all the way. 181 00:07:44,763 --> 00:07:47,699 Those pi bands are going across the whole surface. 182 00:07:47,699 --> 00:07:50,068 And those electrons are critical. 183 00:07:50,068 --> 00:07:52,037 Those electrons that occupy those [INAUDIBLE] 184 00:07:52,037 --> 00:07:58,009 are critical to the very special properties that graphene has. 185 00:07:58,009 --> 00:08:00,412 So you now know the secret. 186 00:08:00,412 --> 00:08:02,147 It's sp2 hybridization. 187 00:08:02,147 --> 00:08:04,683 And, you know, this has allowed us-- 188 00:08:04,683 --> 00:08:06,852 this has-- you might tell I'm kind of 189 00:08:06,852 --> 00:08:08,186 passionate about this problem. 190 00:08:08,186 --> 00:08:09,721 Partly impassioned passion about a lot of problems 191 00:08:09,721 --> 00:08:11,323 but, also, we happen to work on this, 192 00:08:11,323 --> 00:08:12,991 and we have been developing this. 193 00:08:12,991 --> 00:08:15,093 This is like the ultimate membrane. 194 00:08:15,093 --> 00:08:17,229 I can soak this in chlorine overnight. 195 00:08:17,229 --> 00:08:19,064 I can put it in negative pH solutions. 196 00:08:19,064 --> 00:08:20,465 I can heat it up. 197 00:08:20,465 --> 00:08:22,401 It doesn't degrade. 198 00:08:22,401 --> 00:08:26,405 And we have figured out how to poke holes in it 199 00:08:26,405 --> 00:08:28,607 at just the right size, or to stitch it 200 00:08:28,607 --> 00:08:33,578 together so that maybe you can filter particles by the flow 201 00:08:33,578 --> 00:08:35,313 in between these sheets. 202 00:08:35,313 --> 00:08:37,048 Right. 203 00:08:37,048 --> 00:08:38,650 And this material, as a membrane, 204 00:08:38,650 --> 00:08:41,886 is so promising that we've actually 205 00:08:41,886 --> 00:08:44,623 started to commercialize it as of the last year. 206 00:08:44,623 --> 00:08:46,992 And I think this is really going to make a big difference 207 00:08:46,992 --> 00:08:49,127 in a lot of areas. 208 00:08:49,127 --> 00:08:49,961 Why? 209 00:08:49,961 --> 00:08:52,497 Because of sp2 hybridization. 210 00:08:52,497 --> 00:08:53,598 That is why. 211 00:08:53,598 --> 00:08:56,134 That is why this is such a special material. 212 00:08:56,134 --> 00:08:56,735 OK. 213 00:08:56,735 --> 00:08:58,470 That's my why this matters.